Science technology innovation №2(6) 2018, 61-70 p

PDF

Sverdlikovska O. S. — PhD in Chemistry, Associate professor of Department of processing of plastics, photo-, nanoand polygraphic materials, State higher educational institution “Ukrainian state university of chemical engineering”, 8, Gagarin Av., Dnipro, Ukraine, 49005; +38097-779-59-18; o.sverdlikovska@gmail.com

Burmistr M. V. — Doctor of Science in Chemistry, Professor, Head of Department of processing of plastics, photo-, nano- and polygraphic materials. State higher educational institution “Ukrainian state university of chemical engineering”, 8, Gagarin Av., Dnipro, Ukraine, 49005

Fedenko O. O. — Оperating Director of LLC “Weighing Systems — PROM”, 29, Slobozhansky Str., Dnipro, Ukraine, 49005; oksanka.fedenko@ukr.net

APROTIC POLYMERIC ION LIQUORS OF IONENE TYPE
Abstract. Scientific and practical foundations of synthesis laws of reactive ion-type aprotic polymeric ionic liquids on the basis of polymeric quaternary ammonium salts (morpholine derivatives) of a liquid aggregate state in a wide range of temperatures with high ionic conductivity and the ability to regulate their physical and chemical properties to solve scientific and technical problems of chemistry and chemical technology (problems of the development of electrochemical devices, polymer composite materials, surfactants, etc.) were developed. It is determined that synthesized polymeric ionic liquids of the ion-type are thermo stable compounds with high ionic conductivity (~10–1–10–6 Сm·сm–1) in a wide range of temperatures.

Keywords: polymeric ionic liquids, polymer quaternary ammonium salts, morpholine, ionic conductivity.

REFERENCES
1. Burmistr M.V., Sverdlikovskaya O.S., Burmistr O.M., Fedenko O.A. (2012) Sovremennoe sostoyanie i
osnovnye tendentsii razvitiya perspektivnykh ionnykh zhidkostey [Current state and main trends in the development of promising ionic liquids]. Vestnik Udmurtskogo Universiteta [Bulletin of the Udmurt University], Vol. 1, pp. 55-68.
2. Aslanov L.A., Zakharov M.A., Abramycheva N.L. (2005) Ionnye zhidkosti v ryadu rastvoriteley [Ionic
liquids in a series of solvents]. Moscow (in Russ.): MGU publ., 272 p.
3. Gamstedt H. Ionic Liquid Electrolytes for Photoelectrochemical Solar Cells. Department of Chemistry Royal Institute of Technology Stockholm, Sweden, 2005.
4. Koch V.R., Nanjundiah C., Appetecchi G.B., Scrosati B.J. (1995) The Interfacial Stability of Li with Two New Solvent-Free Ionic Liquids: 1,2-Dimethyl-3-propylimidazolium Imide and Methide. J. Electrochem
Soc. Vol. 142, L116–L118.
5. Noda M.A., Susan B. H., Kudo K., et al. (2003) Brоnsted Acid–Base Ionic Liquids as Proton-Conducting
Nonaqueous Electrolytes. J. Phys. Chem. B. Vol., 107, pp. 4024–4033.
6. Lu W., Fadeev A.G., Qi B., et al. (2002) Use of ionic liquids for pi-conjugated polymer electrochemical
devices. Science, Vol. 297, pp. 983–987.
7. Welton T. (1999) Room-Temperature Ionic Liquids. Solvents for Synthesis and Catalysis. Chem. Rev.
Vol. 99, pp. 2071–2083.
8. Holbrey J.D., Seddon K.R. (1999) Ionic Liquids. Clean Prod. Process. Vol. 1, pp. 223–236.
9. Wassersheid P., Keim W. (2000) Ionic Liquids-New “Solutions” for Transition Metal Catalysis. Int. Ed.
Angew. Chem. Vol. 39, pp. 3772–3789.
10. Anderson J.L., Ding J., Welton T., Armstrong D.W. (2002) Characterizing ionic liquids on the basis of
multiple solvation interactions. J. Am. Chem. Soc., Vol. 124, pp. 14247–14254.
11. Anastas P.T., Warner J.C. (1998) Green Chemistry: Theory and Practice; Oxford University Press: New York, 30 p.
12. Garcia M.T., Gathergood N., Scammells P.J. (2005) Biodegradable ionic liquids Part II. Effect of the anion and toxicology Green. Chem. Vol. 7, pp. 9–14.
13. Wasserscheid P., van Hal R., Busmann A. (2002) 1-n-Butyl-3-methylimidazolium ([bmim]) octylsulfate
— an even ‘greener’ ionic liquid. Green Chem. Vol. 4, pp. 400–404.
14. Ponkratov D.O. Polimernye ionnye zhidkosti [Polymer ionic liquids] dis. of Dr. Sc. in Chem. 02.00.06
“High-molecular compounds” FGBUNIS. Moscow (in Russ.): FGBUNIES Publ., 2014, 196 p.
15. Green Omar, Grubjesic Simonida, Lee Sungwon, Millicent A. Firestone (2009) The Design of Polymeric Ionic Liquids for the Preparation of Functional Materials. Polymer Reviews. Vol. 46, pp. 339–360.
16. Shaplov A.S., Ponkratov D.O., Vlasov P.S., et al. (2013) Synthesis and Properties of Polymeric Analogs of Ionic Liquids. Polymer Science, Ser. B, Vol. 55, no. 3-4, pp. 122-138.
17. Jiayin Yuan, Antonietti Markus (2011) Poly(ionic liquid) s: Polymers expanding classical property profiles.
Polymer. Vol. 52, pp. 1469–1482.
18. Mecerreyes David (2011) Polymeric ionic liquids: Broadening the properties and applications of polyelectrolytes. Polymer. Vol. 36, pp. 1629–1648.
19. Yuan Jiayin, Mecerreyes David, Antonietti Markus (2013) Poly(ionic liquid)s: an update. Progress in
Polymer Science. Vol. 38, pp. 1009–1036.
20. Green Matthew D., Timothy E. Long (2009) Designing Imidazole-Based Ionic Liquids and Ionic Liquid
Monomers for Emerging Technologies. Polymer Rev. Vol. 49, no. 4, pp. 291–314.
21. Shevchenko V.V., Stryutskiy A.V., Klimenko N.S., et al. (2014) Protonnye kationoaktivnye oligomernye
ionnye zhidkosti uretanovogo tipa [Proton cationic oligomeric ionic liquids of urethane type]. High-molecular connections, Ser. B, Vol. 56, no. 5, pp. 480–489.
22. Meiran Xie, Huijing Han, LiangDing, Jiaxin Shi (2009) Promotion of Atom Transfer Radical Polymerization and Ring-Opening Metathesis Polymerization in Ionic Liquids. Polymer Reviews. Vol. 49, pp. 315–338.
23. Sverdlikovska O.S., Burmistr M.V. (2015) Ionic liquids based on polymeric quaternary salts of ammonium
(morpholine derivatives). Synthesis, properties, application. News of Science and Education. Chemistry and Chemical Technology. Vol. 3 (27), pp. 76–83.
24. Sverdlikovskaya O.S., Burmistr M.V., Fedenko O.A. (2014) Poliioneny na osnove proizvodnykh oksiranovykh soedineniy i morfolina. Tezisy doklada X Mezhdunarodnaya nauchno-prakticheskaya konferentsiya “TRANS-MECH-ART-CHEM” [Polyionenes based on derivatives of oxirane compounds and
morpholine / Abstracts of the report X International Scientific and Practical Conference “TRANS-MECHART-CHEM”], pp. 34–36.
25. Burmistr M.V., Burmistr Ye.M. (2005) Alkilaromaticheskie poliioneny [Alkylaromatic polyionenes]
monograph. Dnepropetrovsk (in Ukr.): UGKhTU Publ., 131 p.
26. Noguchi H., Rembaum А. (1969) Cyclic, linear and polymeric ammonium salts. Amer. Chem. Soc. Polymer
reprints. Vol. 10, no. 2, pp. 718–728.
27. Razvodovskiy Ye.F., Nekrasov A.V., Yenikolopyan N.S. (1972) Sintez polimernykh chetvertichnykh am monievykh osnovaniy [Synthesis of polymeric quaternary ammonium bases]. High-molecular connections, Ser. B, Vol. 14, no. 5, pp. 338–340.
28. Tsuchida E., Sanada K., Moribe K. (1972) The mechanism of polymerization and the solvent effect in the formation of polycation polymers of integral type. Macromol. Chem. Vol. 155, pp. 35–44.