{"id":1435,"date":"2019-01-15T14:42:25","date_gmt":"2019-01-15T12:42:25","guid":{"rendered":"http:\/\/nti.ukrintei.ua\/?page_id=1435"},"modified":"2019-07-01T17:11:24","modified_gmt":"2019-07-01T14:11:24","slug":"science-technology-innovation-%e2%84%9626-2018-61-70-p","status":"publish","type":"page","link":"https:\/\/nti.ukrintei.ua\/?page_id=1435&lang=en","title":{"rendered":"Science technology innovation \u21162(6) 2018, 61-70 p"},"content":{"rendered":"<p><a title=\"\u041f\u043e\u043b\u043d\u0430\u044f \u0441\u0442\u0430\u0442\u044c\u044f\" href=\"http:\/\/nti.ukrintei.ua\/wp-content\/uploads\/2019\/07\/2018-2-%D0%A1%D0%B2%D0%B5%D1%80%D0%B4%D0%BB%D0%B8%D0%BA%D0%BE%D0%B2%D1%81%D1%8C%D0%BA%D0%B0.pdf\"><img loading=\"lazy\" class=\"alignnone size-full wp-image-359\" src=\"http:\/\/nti.ukrintei.ua\/wp-content\/uploads\/2018\/05\/pdf-icon.png\" alt=\"\" width=\"32\" height=\"32\" \/>PDF<\/a><\/p>\n<p><strong>Sverdlikovska O. S.<\/strong> \u2014 PhD in Chemistry, Associate professor of Department of processing of plastics, photo-, nanoand polygraphic materials, State higher educational institution \u201cUkrainian state university of chemical engineering\u201d, 8, Gagarin Av., Dnipro, Ukraine, 49005; +38097-779-59-18; o.sverdlikovska@gmail.com<\/p>\n<p><strong>Burmistr M. V.<\/strong> \u2014 Doctor of Science in Chemistry, Professor, Head of Department of processing of plastics, photo-, nano- and polygraphic materials. State higher educational institution \u201cUkrainian state university of chemical engineering\u201d, 8, Gagarin Av., Dnipro, Ukraine, 49005<\/p>\n<p><strong>Fedenko O. O.<\/strong> \u2014 \u041eperating Director of LLC &#8220;Weighing Systems \u2014 PROM&#8221;, 29, Slobozhansky Str., Dnipro, Ukraine, 49005; oksanka.fedenko@ukr.net<\/p>\n<p><strong>APROTIC POLYMERIC ION LIQUORS OF IONENE TYPE<\/strong><br \/>\n<strong>Abstract.<\/strong> Scientific and practical foundations of synthesis laws of reactive ion-type aprotic polymeric ionic liquids on the basis of polymeric quaternary ammonium salts (morpholine derivatives) of a liquid aggregate state in a wide range of temperatures with high ionic conductivity and the ability to regulate their physical and chemical properties to solve scientific and technical problems of chemistry and chemical technology (problems of the development of electrochemical devices, polymer composite materials, surfactants, etc.) were developed. It is determined that synthesized polymeric ionic liquids of the ion-type are thermo stable compounds with high ionic conductivity (~10\u20131\u201310\u20136 \u0421m\u00b7\u0441m\u20131) in a wide range of temperatures.<\/p>\n<p><strong>Keywords:<\/strong> polymeric ionic liquids, polymer quaternary ammonium salts, morpholine, ionic conductivity.<\/p>\n<p><strong>REFERENCES<\/strong><br \/>\n1. Burmistr M.V., Sverdlikovskaya O.S., Burmistr O.M., Fedenko O.A. (2012) Sovremennoe sostoyanie i<br \/>\nosnovnye tendentsii razvitiya perspektivnykh ionnykh zhidkostey [Current state and main trends in the development of promising ionic liquids]. Vestnik Udmurtskogo Universiteta [Bulletin of the Udmurt University], Vol. 1, pp. 55-68.<br \/>\n2. Aslanov L.A., Zakharov M.A., Abramycheva N.L. (2005) Ionnye zhidkosti v ryadu rastvoriteley [Ionic<br \/>\nliquids in a series of solvents]. Moscow (in Russ.): MGU publ., 272 p.<br \/>\n3. Gamstedt H. Ionic Liquid Electrolytes for Photoelectrochemical Solar Cells. Department of Chemistry Royal Institute of Technology Stockholm, Sweden, 2005.<br \/>\n4. Koch V.R., Nanjundiah C., Appetecchi G.B., Scrosati B.J. (1995) The Interfacial Stability of Li with Two New Solvent-Free Ionic Liquids: 1,2-Dimethyl-3-propylimidazolium Imide and Methide. J. Electrochem<br \/>\nSoc. Vol. 142, L116\u2013L118.<br \/>\n5. Noda M.A., Susan B. H., Kudo K., et al. (2003) Br\u043ensted Acid\u2013Base Ionic Liquids as Proton-Conducting<br \/>\nNonaqueous Electrolytes. J. Phys. Chem. B. Vol., 107, pp. 4024\u20134033.<br \/>\n6. Lu W., Fadeev A.G., Qi B., et al. (2002) Use of ionic liquids for pi-conjugated polymer electrochemical<br \/>\ndevices. Science, Vol. 297, pp. 983\u2013987.<br \/>\n7. Welton T. (1999) Room-Temperature Ionic Liquids. Solvents for Synthesis and Catalysis. Chem. Rev.<br \/>\nVol. 99, pp. 2071\u20132083.<br \/>\n8. Holbrey J.D., Seddon K.R. (1999) Ionic Liquids. Clean Prod. Process. 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Polimernye ionnye zhidkosti [Polymer ionic liquids] dis. of Dr. Sc. in Chem. 02.00.06<br \/>\n&#8220;High-molecular compounds&#8221; FGBUNIS. Moscow (in Russ.): FGBUNIES Publ., 2014, 196 p.<br \/>\n15. Green Omar, Grubjesic Simonida, Lee Sungwon, Millicent A. Firestone (2009) The Design of Polymeric Ionic Liquids for the Preparation of Functional Materials. Polymer Reviews. Vol. 46, pp. 339\u2013360.<br \/>\n16. Shaplov A.S., Ponkratov D.O., Vlasov P.S., et al. (2013) Synthesis and Properties of Polymeric Analogs of Ionic Liquids. Polymer Science, Ser. B, Vol. 55, no. 3-4, pp. 122-138.<br \/>\n17. Jiayin Yuan, Antonietti Markus (2011) Poly(ionic liquid) s: Polymers expanding classical property profiles.<br \/>\nPolymer. Vol. 52, pp. 1469\u20131482.<br \/>\n18. Mecerreyes David (2011) Polymeric ionic liquids: Broadening the properties and applications of polyelectrolytes. Polymer. Vol. 36, pp. 1629\u20131648.<br \/>\n19. Yuan Jiayin, Mecerreyes David, Antonietti Markus (2013) Poly(ionic liquid)s: an update. Progress in<br \/>\nPolymer Science. Vol. 38, pp. 1009\u20131036.<br \/>\n20. Green Matthew D., Timothy E. Long (2009) Designing Imidazole-Based Ionic Liquids and Ionic Liquid<br \/>\nMonomers for Emerging Technologies. Polymer Rev. Vol. 49, no. 4, pp. 291\u2013314.<br \/>\n21. Shevchenko V.V., Stryutskiy A.V., Klimenko N.S., et al. (2014) Protonnye kationoaktivnye oligomernye<br \/>\nionnye zhidkosti uretanovogo tipa [Proton cationic oligomeric ionic liquids of urethane type]. High-molecular connections, Ser. B, Vol. 56, no. 5, pp. 480\u2013489.<br \/>\n22. Meiran Xie, Huijing Han, LiangDing, Jiaxin Shi (2009) Promotion of Atom Transfer Radical Polymerization and Ring-Opening Metathesis Polymerization in Ionic Liquids. Polymer Reviews. Vol. 49, pp. 315\u2013338.<br \/>\n23. Sverdlikovska O.S., Burmistr M.V. (2015) Ionic liquids based on polymeric quaternary salts of ammonium<br \/>\n(morpholine derivatives). Synthesis, properties, application. News of Science and Education. Chemistry and Chemical Technology. Vol. 3 (27), pp. 76\u201383.<br \/>\n24. Sverdlikovskaya O.S., Burmistr M.V., Fedenko O.A. (2014) Poliioneny na osnove proizvodnykh oksiranovykh soedineniy i morfolina. Tezisy doklada X Mezhdunarodnaya nauchno-prakticheskaya konferentsiya \u201cTRANS-MECH-ART-CHEM\u201d [Polyionenes based on derivatives of oxirane compounds and<br \/>\nmorpholine \/ Abstracts of the report X International Scientific and Practical Conference &#8220;TRANS-MECHART-CHEM&#8221;], pp. 34\u201336.<br \/>\n25. Burmistr M.V., Burmistr Ye.M. (2005) Alkilaromaticheskie poliioneny [Alkylaromatic polyionenes]<br \/>\nmonograph. Dnepropetrovsk (in Ukr.): UGKhTU Publ., 131 p.<br \/>\n26. Noguchi H., Rembaum \u0410. (1969) Cyclic, linear and polymeric ammonium salts. Amer. Chem. Soc. Polymer<br \/>\nreprints. Vol. 10, no. 2, pp. 718\u2013728.<br \/>\n27. Razvodovskiy Ye.F., Nekrasov A.V., Yenikolopyan N.S. (1972) Sintez polimernykh chetvertichnykh am\u00a0monievykh osnovaniy [Synthesis of polymeric quaternary ammonium bases]. High-molecular connections, Ser. B, Vol. 14, no. 5, pp. 338\u2013340.<br \/>\n28. Tsuchida E., Sanada K., Moribe K. (1972) The mechanism of polymerization and the solvent effect in the formation of polycation polymers of integral type. Macromol. Chem. Vol. 155, pp. 35\u201344.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>PDF Sverdlikovska O. S. \u2014 PhD in Chemistry, Associate professor of Department of processing of plastics, photo-, nanoand polygraphic materials, State higher educational institution \u201cUkrainian state university of chemical engineering\u201d, 8, Gagarin Av., Dnipro, Ukraine, 49005; +38097-779-59-18; o.sverdlikovska@gmail.com Burmistr M. V. \u2014 Doctor of Science in Chemistry, Professor, Head of Department of processing of plastics, &hellip; <\/p>\n<p><a class=\"more-link btn\" href=\"https:\/\/nti.ukrintei.ua\/?page_id=1435&#038;lang=en\">Continue reading<\/a><\/p>\n","protected":false},"author":2,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":[],"_links":{"self":[{"href":"https:\/\/nti.ukrintei.ua\/index.php?rest_route=\/wp\/v2\/pages\/1435"}],"collection":[{"href":"https:\/\/nti.ukrintei.ua\/index.php?rest_route=\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/nti.ukrintei.ua\/index.php?rest_route=\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/nti.ukrintei.ua\/index.php?rest_route=\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/nti.ukrintei.ua\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=1435"}],"version-history":[{"count":2,"href":"https:\/\/nti.ukrintei.ua\/index.php?rest_route=\/wp\/v2\/pages\/1435\/revisions"}],"predecessor-version":[{"id":2061,"href":"https:\/\/nti.ukrintei.ua\/index.php?rest_route=\/wp\/v2\/pages\/1435\/revisions\/2061"}],"wp:attachment":[{"href":"https:\/\/nti.ukrintei.ua\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=1435"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}